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Preheat oven to 400°F/ 200°C. Grease 16 regular muffin cups, and set aside.
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In a large bowl, mix together the flour, sugar, baking powder, baking soda, and half the amount of chopped pecans.
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In a separate bowl, whisk together the buttermilk, mashed bananas, oil, egg, and vanilla.
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Pour wet ingredients over dry ingredients and stir just until blended.
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Spoon batter into muffin cups, filling about three-fourths full.
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Sprinkle tops evenly with remaining chopped pecans.
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Bake for 15-20 minutes or until muffin tops are lightly brown and a toothpick inserted in center comes out clean.
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Allow to cool in pan on wire rack for 15 minutes, then turn out onto rack and cool completely.